Catalysis and Organic Synthesis Laboratory
The Patil Research Group
Department of Chemistry
Indian Institute of Science Education and Research Bhopal
Publications :
150. Enantioselective Merged Gold/Organocatalysis (Invited Article)
Chayanika Pegu, Bidisha Paroi, and Nitin T. Patil*, Chem. Commun., 2024, 60, 3607 - 3623
> Featured in Themed Collection: Chemical Communications HOT Articles 2024
149. Asymmetric Gold Catalysis Enabled by Specially Designed Ligands
Amol B. Gade*, Urvashi, and Nitin T. Patil*, Org. Chem. Front., 2024, 11, 1858 - 1895
148. Unusual Selectivity in Gold-Catalyzed Intermolecular Heck Reactions (Invited Article)
Mahesh B. Thoke and Nitin T. Patil*, Gold Bull., 2023, 56, 159 - 165
147. Gold-Catalyzed Alkenylation and Arylation of Phosphorothioates
Urvashi, Sampoorna Mishra, and Nitin T. Patil*, Chem. Sci., 2023, 14, 13134 - 13139
Preprint - ChemRxiv, 2023, DOI: 10.26434/chemrxiv-2023-0q3fn
146. Molybdenum-Catalyzed Directed Activation of Aryl Chlorides and Fluorides
Somsuvra Banerjee, Naoki Matsushita, Eiichi Nakamura, Nitin T. Patil, Sobi Asako,* Laurean Ilies*
145. Unlocking the Chain-Walking Process in Gold Catalysis
Vivek W. Bhoyare, Akash G. Tathe, Vincent Gandon*, and Nitin T. Patil*
Angew. Chem., Int. Ed., 2023, 62, e202312786
Preprint - ChemRxiv, 2023, DOI: 10.26434/chemrxiv-2023-bzz0k-v2
144. Gold-Catalyzed 1,2-Dicarbofunctionalization of Alkynes with Organohalides
Shashank P. Sancheti, Yukta Singh, Manoj V. Mane*, and Nitin T. Patil*
Angew. Chem., Int. Ed., 2023, 62, e202310493
Preprint - ChemRxiv, 2023, DOI: 10.26434/chemrxiv-2023-wd2l2
143. Electrochemical Gold-Catalyzed 1,2-Difunctionalization of C–C Multiple Bonds
Anil Kumar, Khyati Shukla, Salman Ahsan, Amit Paul, and Nitin T. Patil*
Angew. Chem., Int. Ed., 2023, 62, e202308636
Preprint - ChemRxiv, 2023, DOI: 10.26434/chemrxiv-2023-pkb1n
142. Gold-Based Enantioselective Bimetallic Catalysis (Invited Article)
Shivhar B. Ambegave, Shubham, Tushar R. More, and Nitin T. Patil*
Chem. Commun., 2023, 59, 8007 - 8016
> Featured in Themed Collection: Chemical Communications HOT Articles 2023
141. Gold-Catalyzed Heck Reaction
Vivek W. Bhoyare, E. D. Sosa Carrizo, Chetan C. Chintawar, Vincent Gandon*, and Nitin T. Patil*
J. Am. Chem. Soc., 2023, 145, 8810 - 8816
Preprint - ChemRxiv, 2022, DOI: 10.26434/chemrxiv- 2022-k82h3
> Highlighted in "ChemistryViews"
> Highlighted in "India Science Wire - Vigyan Prasar"
140. Gold-Catalyzed Aryl-Alkenylation of Alkenes
Anil Kumar, Akash Das, and Nitin T. Patil*, Org. Lett., 2023, 25, 2934 - 2938
139. Fluorination of α-Imino Gold Carbenes to Access C3-Fluorinated Aza-Heterocycles
Shashank P. Sancheti, Dibya Jyoti Mondal, and Nitin T. Patil* ACS Catal., 2023, 13, 4391 - 4397
138. Gold-Catalyzed Multicomponent Reactions (Invited Article)
Akash G. Tathe, Sagar S. Saswade, and Nitin T. Patil* Org. Chem. Front., 2023, 10, 2359 - 2384
136. Gold-based Multicatalytic Systems for Enantioselective C-C Bond Forming Reactions
Shashank P. Sancheti, Yukta Singh, and Nitin T. Patil*
Advances in Catalysis (Elsevier), 2023, volume 73, chapter 5
135. Gold Catalysis: A New Contender for Cross-Coupling Reactions with Aryl Halides
(Invited article in AsiaChem - the official magazine of the Federation of Asian Chemical Societies)
Vaibhav Bedi, Puja K. Mahajan, and Nitin T. Patil*, AsiaChem, 2023, 3, 42 - 47
134. Gold-catalyzed Oxidative Cross-coupling Reactions – A Personal Account
(Special Issue on "Chemical Synthesis and Catalysis in India")
Shivhar B. Ambegave and Nitin T. Patil*, Synlett, 2023, 34, 698 - 708
133. BQ-AurIPr: A Redox-Active Anticancer Au(I) Complex that Induces Immunogenic Cell Death
Ravindra D. Mule, Akhilesh Kumar, Shashank P. Sancheti, Beeran Senthilkumar*, Himanshu Kumar*, Nitin T. Patil*, Chem. Sci., 2022, 13, 10779 - 10785
132. AIEgens Based on Anion−π+ Interactions: Design, Synthesis, Photophysical Properties, and their Biomedical Applications (Invited Article)
Apurba Lal Koner,* Deepak Chopra,* and Nitin T. Patil*, ChemBioChem, 2022, 23, e202200320
131. Chiral Ligands for Au(I), Au(III), and Au(I)/Au(III) Redox Catalysis
(Special Issue on "π–Acid Catalysis")
Sampoorna Mishra, Urvashi and Nitin T. Patil*, Isr. J. Chem., 2022, 63, e202200039
130. Enantioselective Redox Gold Catalysis (Invited Article)
Chetan C. Chintawar and Nitin T. Patil*, Gold Bull., 2022, 55, 161 - 168
129. Ligand-Enabled Gold-Catalyzed C(sp2)–S Cross-Coupling Reactions
Akash G. Tathe and Nitin T. Patil*, Org. Lett., 2022, 24, 4459 - 4463
128. Gold-Catalyzed C(sp2)-H Functionalization under Au(I)/Au(III) Catalysis
Urvashi, Pallavi Singh and Nitin T. Patil, Handbook of C-H Functionalization; Maiti, D., Ed.; Wiley-VCH: Weinheim, 2022, DOI: 10.1002/9783527834242.chf0100
127. Gold Catalysis in Organic Synthesis: Fifteen Years of Research in India (Invited Article)
Debasish Mandal, Anil Kumar and Nitin T. Patil*, Proc. Indian Natl. Sci. Acad., 2022, 88, 501 – 527
126. Enantioselective Au(I)/Au(III) Redox Catalysis Enabled by Chiral (P,N)-Ligands
Chetan C. Chintawar, Vivek W. Bhoyare, Manoj V. Mane and Nitin T. Patil*
J. Am. Chem. Soc., 2022,144, 7089 - 7095
125. Ligand-Enabled Sustainable Gold Catalysis
(Special Issue on Sustainable Chemo- and Bio-Catalysis: From Academia to Industry)
Anil Kumar and Nitin T. Patil*, ACS Sustain. Chem. Eng., 2022, 10, 6900 - 6918
Ravindra D. Mule, Rupam Roy, Koushik Mandal, Deepak Chopra*, Tanoy Dutta, Shashank P. Sancheti, Popat S. Shinde, Somsuvra Banerjee, Apurba Lal Koner,* Rohit Bhowal, Beeran Senthilkumar*, and Nitin T. Patil*, Chem. Eur. J., 2022, 28, e202200632
123. Enantioselective C-H Functionalization Reactions under Gold Catalysis
Avishek Das and Nitin T. Patil*, Chem. Eur. J., 2022, 28, e202104371
122. Gold-Catalyzed 1,2-Aminoarylation of Alkenes with External Amines
Akash G. Tathe, Urvashi, Amit K. Yadav, Chetan C. Chintawar and Nitin T. Patil*
Vivek W. Bhoyare, Akash G. Tathe, Avishek Das, Chetan C. Chintawar and Nitin T. Patil*
120. Recent Advances in Transition-Metal Catalysis (Special Issue on “Transition-Metal Catalysis” )
Hideki Yorimitsu, Martin Kotora and Nitin T. Patil, Chem. Rec., 2021, 21, 3335 - 3337
119. 1,2-Aminofunctionalization Reactions of Pyridino-Alkynes via Carbophilic Activation
(Special Issue on “Transition-Metal Catalysis” edited by Hideki Yorimitsu, Martin Kotora and Nitin T. Patil)
Bidisha Paroi, Shashank P. Sancheti and Nitin T. Patil*, Chem. Rec., 2021, 21, 3779 - 3794
118. Divergent Gold Catalysis: Unlocking Molecular Diversity through Catalyst Control
(Special Issue on “Gold Chemistry” edited by Prof. A. Stephen K. Hashmi)
Chetan C. Chintawar, Amit K. Yadav, Anil Kumar, Shashank P. Sancheti and Nitin T. Patil*
117. Non-Canonical Reactivity of Gold Carbene with Alkyne: An Overview of the Mechanistic Premise
Shashank P. Sancheti and Nitin T. Patil*, Eur. J. Org. Chem., 2021, 1321 - 1330
116. Chloro[di(1-adamantyl)-2-dimethylaminophenylphosphine]gold(I)
Amit K. Yadav, and Nitin T. Patil*, Encyclopedia of Reagents for Organic Synthesis (EROS), 2021 DOI: 10.1002/047084289X.rn02392
115. Ligand-Enabled Gold-Catalyzed 1,2-Heteroarylation of Alkenes
Akash G. Tathe, Chetan C. Chintawar, Vivek W. Bhoyare and Nitin T. Patil*
114. Gold-Catalyzed Alkynylative Meyer-Schuster Rearrangement
Somsuvra Banerjee, Shivhar B. Ambegave, Ravindra D. Mule, Beeran Senthilkumar* and Nitin T. Patil*, Org. Lett., 2020, 22, 4792 - 4796
113. Gold-Catalyzed 1,2-Diarylation of Alkenes
Chetan C. Chintawar, Amit K. Yadav and Nitin T. Patil*, Angew. Chem., Int. Ed., 2020, 59, 11808 - 11813
Somsuvra Banerjee, Vivek W. Bhoyare and Nitin T. Patil*, Chem. Commun., 2020, 56, 2677 - 2690
> Featured in "Organic Synthesis" Collection
> Featured in "ChemComm Community - Dedicated Authors" Collection
111. Ternary Catalysis: A Stepping Stone Towards Multicatalysis
Shashank P. Sancheti, Urvashi, Mosami P. Shah and Nitin T. Patil*, ACS Catal., 2020, 10, 3462 - 3489
110. Solvent-Assisted Monomeric Molecular Structure of the Phosphate Diester and the Synthesis of Menthol-Based Phosphate Diesters (Special Issue on 150 Years of the Periodic Table)
Debdeep Mandal, Vivek Gupta, Biswajit Santra, Nicolas Chrysochos, Vivek W. Bhoyare, Avijit Maiti, Abhishek Kar, Suman, Anku Guha, Pallavi Thakur, Ramakirushnan Suriya Narayanan, Nitin T. Patil*, Carola Schulzke*, Vadapalli Chandrasekhar* and Anukul Jana*, J. Chem. Sci., 2019, 131:121, doi:10.1007/s12039-019-1712-8
Shashank P. Sancheti, Manjur O. Akram, Rupam Roy, Vaibhav Bedi, Shubhankar Kundu and Nitin T. Patil*, Chem. Asian J., 2019, 14, 4601 - 4606
108. Ligand-Enabled Gold-Catalyzed C(sp2)–N Cross-Coupling Reactions of Aryl Iodides with Amines
Manjur O. Akram, Avishek Das, Indradweep Chakrabarty and Nitin T. Patil*
Chetan C. Chintawar, Manoj V. Mane, Akash G. Tathe, Suprakash Biswas and Nitin T. Patil*
106. External Oxidant-Dependent Reactivity Switch in Copper-Mediated Intramolecular Carboamination of Alkynes: Access to New Classes of Fluorescent Ionic Nitrogen-Doped Polycyclic Aromatic Hydrocarbons
Aslam C. Shaikh, Somsuvra Banerjee, Ravindra D. Mule, Saibal Bera and Nitin T. Patil*
J. Org. Chem., 2019, 84, 4120​ - 4130
105. Gold Dual Catalysis with Palladium, Nickel, or Rhodium
Nitin T. Patil, Akash G. Tathe, Vivek W. Bhoyare, Science of Synthesis: Dual Catalysis in Organic Synthesis, Molander, G. A., Ed.; Thieme: Stuttgart, (2019); Vol. 1, p 117 - 162; DOI: 10.1055/sos-SD- 231-00061
104. Ionic Pyridinium-Oxazole Dyads: Design, Synthesis and their Application in Mitochondrial Imaging
Aslam C. Shaikh, Mokshada E. Varma, Ravindra D. Mule, Somsuvra Banerjee, Prasad P. Kulkarni* and Nitin T. Patil*, J. Org. Chem., 2019, 84, 1766 - 1777
Pradip N. Bagle, Manoj V. Mane, Shashank P. Sancheti, Amol B. Gade, Samir R. Shaikh, Mu-Hyun Baik* and Nitin T. Patil*, Org. Lett., 2019, 21, 335 - 339
102. Gold-Catalyzed 1,2-Oxyalkynylation of N-Allenamides with Ethynylbenziodoxolones
Somsuvra Banerjee, Beeran Senthilkumar and Nitin T. Patil*, Org. Lett., 2019, 21, 180 - 184
Ravindra D. Mule, Aslam C. Shaikh, Amol B. Gade and Nitin T. Patil*
100. Oxidant-free Oxidative Gold Catalysis: The New Paradigm in Cross-Coupling Reactions
Manjur O. Akram, Somsuvra Banerjee, Sagar S. Saswade, Vaibhav Bedi and Nitin T. Patil*, Chem. Commun., 2018, 54, 11069 - 11083
Indradweep Chakrabarty, Manjur O. Akram, Suprakash Biswas and Nitin T. Patil*
98. Gold(I)-Catalyzed Cross-Coupling Reactions of Aryldiazonium Salts with Organostannanes
Manjur O. Akram, Popat S. Shinde, Chetan C. Chintawar and Nitin T. Patil*
97. Catalytic Enantioselective 1,3-Alkyl Shift in Alkyl Aryl Ethers: Efficient Synthesis of Optically Active 3,3'-Diaryloxindoles
Amol B. Gade, Pradip N. Bagle, Popat S. Shinde, Vipin Bhardwaj, Subhrashis Banerjee, Ajit Chande and Nitin T. Patil*, Angew. Chem., Int. Ed., 2018, 57, 5735 - 5739
96. Intramolecular Ipso-Arylative Cyclization of Aryl-Alkynoates and N-Arylpropiolamides with Aryldiazonium Salts through Merged Gold/Visible Light Photoredox Catalysis
Avinash H. Bansode, Samir R. Shaikh, Rajesh G. Gonnade and Nitin T. Patil*
95. Exploiting the Dual Role of Ethynylbenziodoxolones in Gold-Catalyzed C(sp)-C(sp) Cross-Coupling Reactions
Somsuvra Banerjee and Nitin T. Patil*, Chem. Commun., 2017, 53, 7937 - 7940.
94. Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible Light Photoredox Catalysis
Manjur O. Akram, Pramod S. Mali and Nitin T. Patil*, Org. Lett., 2017,19, 3075 - 3078
93. Gold-Catalyzed Dehydrazinative C(sp)-Sulphur Coupling Reactions of Arylsulfonyl Hydrazides with Ethynylbenziodoxolones (EBXs) for Accessing Alkynyl Sulfones
Popat S. Shinde and Nitin T. Patil*, Eur. J. Org. Chem., 2017, 24, 3512 - 3515.
92. Catalytic Enantioselective Aza-Piancatelli Rearrangement
Amol B. Gade and Nitin T. Patil*, Synlett., 2017, 28, 1096 - 1100
91. Synthesis of Annulated Bis-indoles through Au(I)/Brønsted Acid-Catalyzed Reactions of (1H-indol-3-yl) (aryl)methanols with 2-(arylethynyl)-1H-indoles
Suleman M. Inamdar, Rajesh G. Gonnade and Nitin T. Patil*
90. Oxidative Intramolecular 1,2-Amino-oxygenation of Alkynes under Au(I)/Au(III) - Catalysis: Discovery of Pyridinium-Oxazole Dyad as Novel Ionic Fluorophore
Aslam C. Shaikh, Dnyanesh S. Ranade, P. R. Rajamohanan, Prasad P. Kulkarni and Nitin T. Patil*, Angew. Chem., Int. Ed., 2017, 56, 757 - 761.
89. [3+2]-Annulation of Platinum-Bound Azomethine Ylides with Distal C=C Bonds of N-Allenamides
Indradweep Chakrabarty, Suleman M. Inamdar, Manjur O. Akram, Amol B. Gade, Subhrasish Banerjee, Saibal Bera and Nitin T. Patil*
88. Catalytic Branching Cascades in Diversity Oriented Synthesis
Avinash H. Bansode, Prathyusha Chimala and Nitin T. Patil*, ChemCatChem., 2017, 9, 30 - 40.
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87. Au(I)/Ag(I) Co-operative Catalysis: Interception of Ag-Bound Carbocations with alpha-Gold(I) Enals in the Imino-Alkyne Cyclizations with N-allenamides
Pradip N. Bagle, Manoj V. Mane, K. Vanka, Dinesh R. Shinde, Samir R. Shaikh, Rajesh G. Gonnade and Nitin T. Patil*, Chem. Commun., 2016, 52, 14462 - 14465.
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86. A Facile Strategy for Accessing 3-Alkynylchromones through Gold-Catalyzed Alkynylation/Cyclization of o-Hydroxyarylenaminones
Manjur O. Akram, Saibal Bera and Nitin T. Patil*, Chem. Commun., 2016, 52, 12306 - 12309.
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85. Efficient Access to Alkynylated Quinalizinones via Gold(I)- catalyzed Aminoalkynylation of Alkynes
Popat S. Shinde, Aslam C. Shaikh and Nitin T. Patil*, Chem. Commun., 2016, 52, 8152 - 8155.
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84. Gold(I)-catalyzed Hydroaminaloxylation and Petasis-Ferrier Rearrangement Cascade of Aminaloalkynes
Amol B. Gade and Nitin T. Patil*, Org. Lett., 2016, 18, 1844 - 1847.
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83. A Unified Approach to Pyrrole-Embedded Aza-Heterocyclic Scaffolds Based on RCM/Isomerization/Cyclization Cascade Catalyzed by Ru/B-H Binary Catalyst System
Suleman M. Inamdar, Indradweep Chakrabarty and Nitin T. Patil*, RSC Advances., 2016, 6, 34428 - 34433.
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82. Gold vs Rhodium Catalysis: Tuning Reactivity through Catalyst Control in the C-H Alkynylation of Isoquinolones
Aslam C. Shaikh, Dinesh R. Shinde and Nitin T. Patil*, Org. Lett., 2016, 18, 1056 - 1059.
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81. Scandium Triflate Catalyzed Unexpected Cleavage of C-C Bonds in Ynones
Rahul D. Kavthe, Avinash H. Bansode and Nitin T. Patil*, ARKIVOC., 2016, 223 - 232.
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80. Highly Emissive Organic Solids with Remarkably Broad Color Tunability Based on N, C Chelate Four-Coordinate Organoborons
Aslam C. Shaikh, Dnyanesh S. Ranade, Shridhar Thorat, Arunava Maity, Prasad P. Kulkarni, Rajesh G. Gonnade and Parthapratim Munshi and Nitin T. Patil*, Chem. Commun., 2015, 51, 16115 - 16118.
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79. Enantioselective Cooperative Catalysis
Suleman M. Inamdar, Valmik S. Shinde and Nitin T. Patil*, Org. Biomol. Chem., 2015, 13, 8116 - 8162.
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78. Identifying Solid Luminogens through Gold-catalyzed Intramolecular Hydroarylation of Alkynes
Aslam C. Shaikh, S. Shalini, Ramanathan Vaidhyanathan, Manoj V. Mane, Ayan Kumar Barui, Chitta Ranjan Patra, Yeduru Venkatesh, Prakriti Ranjan Bangal and Nitin T. Patil*, Eur. J. Org. Chem., 2015, 22, 4860 - 4867.
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77. Engineering Ligands on Au Center: Discovering Broadly Applicable Gold Catalysis with High Turn Over Numbers
Suleman M. Inamdar and Nitin T. Patil*, Org. Chem. Front., 2015, 2, 995 - 998.
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76. Robustness Screen in Enantioselective Catalysis Enabled Generation of Enantioenriched Heterocyclic Scaffolds in One-pot
Pradip N. Bagle, Valmik S. Shinde and Nitin T. Patil*, Chem. Eur. J., 2015, 21, 3580 - 3584.
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75. Catalyst Dependent Selectivity in Relay Catalytic Branching Cascade
Avinash H. Bansode, Aslam C. Shaikh, Rahul D. Kavthe, Shridhar Thorat, Rajesh G. Gonnade and Nitin T. Patil*, Chem. Eur. J., 2015, 21, 2319 - 2323.
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74. Gold(I)/Chiral Brønsted Acid Catalyzed Enantioselective Hydroamination-Hydroarylation of Alkynes: Effect of Remote Hydroxyl Group in the Reactivity and Enantioselectivity
Valmik S. Shinde, Manoj V. Mane, Kumar Vanka, Arijit Mallick and Nitin T. Patil*, Chem. Eur. J., 2015, 21, 975 - 979.
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73. When Gold Meets Chiral Brønsted Acid Catalysts: Extending the Boundaries of Enantioselective Gold Catalysis
Suleman M. Inamdar, Ashok Konala and Nitin T. Patil*, Chem. Commun., 2014, 50, 15124 - 15135.
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72. Enantioselective Heterogeneous Brønsted Acid Catalysis
Anil Kumar Mutyala and Nitin T. Patil*, Org. Chem. Front., 2014, 1, 582 - 586.
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71. Relay Catalytic Branching Cascade: A Technique to Access Diverse Molecular Scaffolds
Nitin T. Patil*, Valmik S. Shinde and B. Sridhar, Angew. Chem. Int. Ed., 2013, 52, 2251 - 2255.
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70. Electrophile induced branching cascade: a powerful approach to access various molecular scaffolds and their exploration as novel anti-mycobacterial agents
Nitin T. Patil*, Ashok Konala, S. Sravanti, A. Singh, R. Ummanni and B. Sridhar, Chem. Commun., 2013, 49, 10109 - 10111.
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​69. The Power of Gold Beyond Glitter: Homogeneous Catalysis with Au(I)-Complexes to Generate a Library of Privileged Scaffolds
Nitin T. Patil*, Current Science., 2013, 104, 1671 - 1680.
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68. Enantioselective Cooperative Triple Catalysis: Unique Roles of Au(I)/Amine/Chiral Bronsted Acid Catalysts in the Addition/Cycloisomerization/Transfer Hydrogenation Cascade
Nitin T. Patil*, Vivek S. Raut and Ramesh B. Tella, Chem. Commun., 2013, 49, 570 - 572.
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67. A One-pot Catalysis: The Strategic Classification with Some Recent Examples
Nitin T. Patil*, Valmik S. Shinde and Balakrishna Gajula, Org. Biomol. Chem., 2012, 10, 211 - 224.
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​66. Novel Linearly and Angularly Fused Quinazolinones: Synthesis through Gold-Catalyzed Cascade Reactions and Anticancer Activities
Nitin T. Patil*, Pediredla G. V. V. Lakshmi, Balasubramanian Sridhar, Sujata Patra, Manika Pal Bhadra and Chitta Ranjan Patra*, Eur. J. Org. Chem., 2012, 1790 - 1799.
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65. Tuning the Reactivity of Au-Complexes in Au(I)/Chiral Bronsted Acid Cooperative Catalytic System: An Approach to Optically Active Fused 1,2-Dihydroisoquinolines
Nitin T. Patil*, Anil Kumar Mutyala, Ashok Konala and Ramesh Babu Tella, Chem. Commun., 2012, 48, 3094 - 3096.
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64. Au(I)-Catalyzed Unprecedented Rearrangement Reaction Between 2-Amino benzaldehyde with Propargyl Amines: An Expedient Route to 3-Aminoquinolines
Nitin T. Patil*, Vivek S. Raut, Valmik S. Shinde, Gaddamanugu Gayatri and G. Narahari Sastry, Chem. Eur. J., 2012, 18, 5530 - 5535.
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63. Chirality Transfer and Memory of Chirality in Gold-Catalyzed Reactions
Nitin T. Patil*, Chem. Asian J., 2012, 7, 2186 - 2194.
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62. Transition Metal-Catalyzed Direct Addition of Various Pronucleophiles to Unactivated C-C Multiple Bonds
Nitin T. Patil*, Rahul D. Kavthe and Valmik S. Shinde, Tetrahedron., 2012, 68, 8079 - 8146.
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61. Aminoindolines Vs. Quinolines: Mechanistic Insights into the Reaction Between 2-Aminobenzaldehydes and Terminal Alkynes in the Presence of Metals and Secondary Amines, Nitin T. Patil*, A. Nijamudheen and Ayan Datta*, J. Org. Chem., 2012, 77, 6179 - 6185.
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60. Exploiting Higher Alkynophilicity of Au-Species: Developement of Highly Selective Fluorescent Probe for Gold Ions
Nitin T. Patil*, Valmik S. Shinde, Milind S. Thakare, P. Hemant Kumar, Prakriti R. Bangal*, Ayan K. Barui and Chitta R. Patra*, Chem. Commun., 2012, 48, 11229 - 11231.
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59. Merging NHC- and Metal Catalysis: On the Way to Discovering Enantioselective Organic Transformations
Nitin T. Patil*, Angew. Chem., Int. Ed., 2011, 50, 1759 - 1761.
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58. Alkyne Hydroamination Triggered Cyclizations: A Powerful Tool for the Construction of Biologically Important Structural Motifs
Nitin T. Patil* and Vipender Singh, J. Organomet. Chem., 2011, 696, 419 - 432.
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57. Heterogeneous Pi-Acid Catalysis with Metal NPs
Nitin T. Patil*, ChemCatChem., 2011, 3, 1121 - 1125.
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​56. Synthesis of 1,3,5-Trisubstituted Pyrazolines via Zn(II)-Catalyzed Double Hydroamination of Enynes with Aryl Hydrazines
Nitin T. Patil* and Vipender Singh, Chem. Commun., 2011, 47, 11116 - 11118.
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55. Mechanistic Dichotomy with Alkynes in the Formal Hydrohydrazination/Fischer Indolization Tandem Catalyzed by Ph3PAuNTf2/pTSA Binary Catalytic System
Nitin T. Patil* and Ashok Konala, Eur. J. Org. Chem., 2010, 35, 6831 - 6839.
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​54. Metal-Catalyzed Intramolecular Heteroatom (X) to Carbon (C) Functional Group Migration Reactions Involving Addition of X-Y Bonds Across Alkynes
Nitin T. Patil*, Rahul D. Kavthe and Yoshinori Yamamoto*, Advances in Heterocyclic Chemistry., 2010, 101, 75 - 95.
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53. Gold(I)-Catalyzed One-pot Reactions Between 2-Aminophenyl Alkynes and Alkynols Leading to the Formation of C-3 Substituted Indoles: A Case of Formal Carboamination of Alkynes
Nitin T. Patil*, Vipender Singh, Ashok Konala and Anil Kumar Mutyala, Tetrahedron Lett., 2010, 51, 1493 - 1496.
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​52. Au(I)-Catalyzed Direct Hydroamination-Hydroarylation and Double Hydroamination Reactions of Terminal Alkynes
Nitin T. Patil*, P. G. V. V. Lakshmi and Vipender Singh, Eur. J. Org. Chem., 2010, 4719 - 4731.
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51. Facile Assembly of Fused Isoquinolines by Gold(I)-Catalyzed Coupling–Cyclization Reactions between o-Alkynylbenzaldehydes and Aromatic Amines Containing Tethered Nucleophiles
Nitin T. Patil*, Anil Kumar Mutyala, P. G. V. V. Lakshmi, P. V. K. Raju and Balasubramanian Sridhar, Eur. J. Org. Chem., 2010, 1999 - 2007.
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50. Cooperative Catalysis with Metal and Secondary Amine: Efficient Synthesis of 2-Substituted Quinolines via Cascade Addition/Cycloisomerization Approach
Nitin T. Patil* and Vivek Raut, J. Org. Chem., 2010, 75, 6961 - 6964.
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49. Au(I)-Catalyzed Cascade Reaction Involving Formal Double Hydroamination of Alkynes Bearing Tethered Carboxylic Groups: An Easy Access to Fused Dihydrobenzimidazoles and Tetrahydroquinazolines
Nitin T. Patil*, Anil Kumar Mutyala, P. G. V. V. Lakshmi, B. Gajula, Balasubramanian Sridhar, G. Potireddygari and Tadikamalla P. Rao, J. Org. Chem., 2010, 75, 5963 - 5975.
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48. Pt(IV)-catalyzed Hydroamination-Triggered Cyclization: A Strategy to Fused Pyrrolo[1,2-a]quinoxalines, Indolo[1,2-a]quinoxalines and Indolo[3,2-c]quinolines
Nitin T. Patil*, Rahul D. Kavthe, Valmik S. Shinde and Balasubramanian Sridhar, J. Org. Chem., 2010, 75, 3371 - 3380.
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47. Gold- and Platinum-Catalyzed Formal Markownikoff's Double Hydroamination of Alkynes: A Rapid Access to trahydroquinazolinones and Angularly-Fused Analogues
Nitin T. Patil*, Rahul D. Kavthe, Vivek S. Raut, Valmik S. Shinde and Balasubramanian Sridhar, J. Org. Chem., 2010, 75, 1277 - 1280.
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46. Alkyne Activation with Brønsted acids, iodine or gold complexes, and Its Fate Leading to Synthetic Application
Yoshinori Yamamoto*, Ilya D. Gridnev, Nitin T. Patil and Tienan Jin, Chem. Commun., 2009, 45, 5075 - 5087.
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​45. Thorpe-Ingold Effect in Copper(II)-catalyzed Formal Hydroalkoxylation-Hydroarylation Reaction of Alkynols with Indoles
Nitin T. Patil*, Vivek S. Raut, Rahul D. Kavthe, Vaddu V. N. Reddy and P. V. K. Raju, Tetrahedron Lett., 2009, 50, 6576 - 6579.
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44. Highly Selective Electrophile-Induced Cascade Reactions between o-Alkynylbenzaldehydes and Styrene Oxides Leading to the Formation of 1-Naphthyl Ketones
Nitin T. Patil*, Ashok Konala, Vipender Singh and Vaddu V. N. Reddy, Eur. J. Org. Chem., 2009, 5178 - 5184.
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43. Transition Metal-Catalyzed Cyclization Reactions of Functionalized Alkenes, Alkynes, and Allenes, Handbook of Cyclization Reactions
Nitin T. Patil* and Yoshinori Yamamoto*, Ma, S., Eds.; Wiley-VCH: Weinheim, Chapter 9, (2009).
42. Platinum-catalyzed Formal Markownikoff's- hydroamination/Hydroarylation Cascade of Terminal Alkynes Assisted by Tethered Hydroxyl Groups
Nitin T. Patil*, Rahul D. Kavthe, Vivek S. Raut and Vaddu V. N. Reddy, J. Org. Chem., 2009, 74, 6315 - 6318.
Patents :
​41. Optically Active (P,N)-ligands and their Applications in Metal Catalysis
Chetan C. Chintawar, Vivek W. Bhoyare, and Nitin T. Patil, Application Number: 202221009636; Filing Date: 23-02-2022
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40. New Redox-Active Benzoquinolizinium-Gold(I) Complexes
Ravindra D. Mule, Beeran Senthilkumar and Nitin T. Patil, Application Number: 202111046230
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39. Novel Solid State Emitters Based on Pyridinium Scaffolds
Ravindra D. Mule, Beeran Senthilkumar and Nitin T. Patil, Application Number: 202111040211
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38. Pyridinium Oxazole Dyad Scaffold and a Process for Preparation Thereof
A. C. Shaikh, D. S. Ranade, P. P. Kulkarni and Nitin T. Patil, U. S. Patent: US10711012B2; US11021490B2; WIPO (PCT): WO2018073838A1; Indian Patent: IN 201611035581
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37. N,C-Chelate Four-Coordinate Organoborons with Full Color Tunability
Aslam C. Shaikh and Nitin T. Patil, U. S. Patent: US10301330B2; WIPO (PCT): WO2016207910A1; Indian Patent: IN 2015DE01844
Publications from Post-Doctoral Work :
36. Iodine-Mediated Electrophilic Cyclization of 2-Alkynyl-1-methylene Azide Aromatics Leading to Highly Substituted Isoquinolines and its Application to the Synthesis of Norchelerythrine
Dirk Fischer, Hisamitsu Tomeba, Nirmal K. Pahadi, Nitin T. Patil, Zhibao Huo and Yoshinori Yamamoto*, J. Am. Chem. Soc., 2008, 130, 15720 - 15725.
35. Coinage Metal Assisted Synthesis of Heterocycles
Nitin T. Patil and Yoshinori Yamamoto*, Chem. Rev., 2008, 108, 3395 - 3442.
34. Synthesis of 1,3,4-Trisubstituted Isoquinolines by Iodine-Mediated Electrophilic Cyclization of 2-Alkynyl Benzyl Azides
Dirk Fischer, Hisamitsu Tomeba, Nirmal K. Pahadi, Nitin T. Patil and Yoshinori Yamamoto*, Angew. Chem., Int. Ed., 2007, 46, 4764 - 4766.
33. Suppression of β-Hydride Elimination in the Intramolecular Hydrocarboxylation of Alkynes Leading to the Formation of Lactones
Zhibao Huo, Nitin T. Patil, Tienan Jin, Nirmal K. Pahadi and Yoshinori Yamamoto*, Adv. Synth. Catal., 2007, 349, 680 - 684.
32. A New Route to Tetrahydroquinolines via Palladium-Catalyzed Intramolecular Hydroamination of Alkynes
Nitin T. Patil, Huanyou Wu and Yoshinori Yamamoto*, J. Org. Chem., 2007, 72, 6577 - 6579.
31. Palladium Catalyzed Three Component Coupling Reactions Between Chromones, Alcohols and Allylic Acetates: Diversity Oriented Synthesis of Highly Substituted Chromones
Nitin T. Patil, Zhibao Huo and Yoshinori Yamamoto*, Tetrahedron, 2007, 63, 5954 - 5961.
30. Palladium Catalyzed Reactions of Highly Activated Olefins
Nitin T. Patil and Yoshinori Yamamoto*, Synlett, 2007, 1994 - 2005.
29. Metal-Mediated Synthesis of Furans and Pyrroles (Dedicated to Professor Alan Krief on the Occasion of his 65th Birthday)
Nitin T. Patil and Yoshinori Yamamoto*, Arkivoc, 2007, 121 - 141.
28. Gold-Catalyzed Reactions of Oxo-alkynes (Dedicated to Professor Lutz Tietze on the Occasion of his 65th Birthday)
Nitin T. Patil and Yoshinori Yamamoto*, Arkivoc, 2007, 6 - 19.
27. Palladium Catalyzed Allylation of Pronucleophiles with Alkynes at 50 °C: Remarkable Effect of 2-(Dicyclohexylphosphino)-2'-(N,N-dimethylamino)biphenyl as Ligand
Nitin T. Patil, Dschun Song and Yoshinori Yamamoto*, Eur. J. Org. Chem., 2006, 4211 - 4213.
26. Gold Catalyzed Intramolecular Hydroamination of Allenes: A Case of Chirality Transfer
Nitin T. Patil, Léopold MpakaLutete, Naoko Nishina and Yoshinori Yamamoto*, Tetrahedron Lett., 2006, 47, 4749 - 4751 (Received Most Cited Paper 2006-2009 Award)
25. Allyltributylstannane: An Update
Nitin T. Patil and Yoshinori Yamamoto*, Encyclopedia of Reagents for Organic Synthesis; Paquette, L., Ed.; Willey: New York. 2006.
24. Umpolung of π-Allylpalladium Complexes
Nitin T. Patil and Yoshinori Yamamoto*, J. J. Chem., 2006, 1, 13 - 23.
23. Palladium Catalyzed Cascade Reactions Involving π-Allyl Palladium Chemistry
Nitin T. Patil and Yoshinori Yamamoto*, Topics in Organometallic Chemistry, 2006, 19, 91 - 113.
22. Palladium-Catalyzed Decarboxylative Aza-Michael Addition-Allylation Reactions between Allyl Carbamates and Activated Olefins. Generation of Quaternary Carbon Adjacent to Secondary Amine Carbon Center
Nitin T. Patil, Zhibao Huo and Yoshinori Yamamoto*, J. Org. Chem., 2006, 71, 6991 - 6995.
21. Palladium-Catalyzed Intramolecular Asymmetric Hydroamination, Hydroalkoxylation and Hydrocarbonation of Alkynes
Nitin T. Patil, Léopold Mpaka Lutete, Huanyou Wu, Nirmal K. Pahadi, Ilya D. Gridnev and Yoshinori Yamamoto*, J. Org. Chem., 2006, 71, 4270 - 4279.
20. Lactam Synthesis via Intramolecular Hydroamidation of Alkynes Catalyzed by Palladium Complexes
Nitin T. Patil, Zhibao Huo, Gan B. Bajracharya and Yoshinori Yamamoto*, J. Org. Chem., 2006, 71, 3612 - 3614.
19. β-Alkyl-α-allylation of Michael Acceptors through the Palladium Catalyzed Three Component Coupling between Allylic Substrates, Trialkylboranes and Activated Olefins
Nitin T. Patil, Zhibao Huo and Yoshinori Yamamoto*, J. Org. Chem., 2006, 71, 2503 - 2506.
18. Silver (I) Catalyzed Novel Cascade Cyclization Reactions: Incorporation of Allenes into the Isochromenes
Nitin T. Patil, Nirmal K. Pahadi and Yoshinori Yamamoto*, J. Org. Chem., 2005, 70, 10096 - 10098.
17. Cu(I) Catalyst in DMF: An Efficient Catalytic System for the Synthesis of Furans from 2-(1-Alkynyl)-2-alken-1-ones
Nitin T. Patil, Huanyou Wu and Yoshinori Yamamoto*, J. Org. Chem., 2005, 70, 4531 - 4534.
16. Progress in the Total Synthesis of Laurencin and Prelaureatin
Nitin T. Patil and Yoshinori Yamamoto*, Rec. Res. Develop. Org. Chem., 2005, 9, 131 - 146.
15. A Novel Route to the Synthesis of Indolizidine (–)-209D: Excellent Diastereoselectivity in the Intramolecular Hydroamination of Alkynes
Nitin T. Patil, Nirmal K. Pahadi and Yoshinori Yamamoto*, Tetrahedron Lett., 2005, 46, 2101 - 2103.
14. Pd(0)/PhCOOH Catalyzed Addition of O-Nucleophiles to Allenes and Internal Alkynes (Professor Howard Alper Commemorative Issue)
Nitin T. Patil, Nirmal K. Pahadi and Yoshinori Yamamoto*, Can. J. Chem., 2005, 83, 569 - 573.
13. A Convenient and Efficient Route for the Allylation of Aromatic Amines and α-Aryl Aldehydes with Alkynes in the Presence of a Pd(0)/PhCOOH Combined Catalyst System Nitin T. Patil, Huanyou Wu, Isao Kadota and Yoshinori Yamamoto*, J. Org. Chem., 2004, 69, 8745 - 8750.
12. Formation of a Quaternary Carbon Center through the Pd(0)/PhCOOH Catalyzed Allylation of Cyclic β-Keto Esters and 1,3-Diketones with Alkynes
Nitin T. Patil and Yoshinori Yamamoto*, J. Org. Chem., 2004, 69, 6478 - 6481.
11. Synthesis of Cyclic Alkenyl Ethers via Intramolecular Cyclization of O-Alkynylbenzaldehydes. Importance of Combination between CuI Catalyst and DMF
Nitin T. Patil and Yoshinori Yamamoto*, J. Org. Chem., 2004, 69, 5139 - 5142.
10. Microwave-Enhanced Pd(0)/Acetic Acid Catalyzed Allylation Reactions of C, Nand O-Pronucleophiles with Alkynes
Nitin T. Patil, F. Nawaz Khan and Yoshinori Yamamoto*, Tetrahedron Lett., 2004, 45, 8497 - 8499.
9. Direct Allylic Substitution of Allyl Alcohols by Carbon Pronucleophiles in the Presence of a Palladium/CarboxylicAcid Catalyst under Neat Conditions
Nitin T. Patil and Yoshinori Yamamoto*, Tetrahedron Lett., 2004, 45, 3101 - 3103.
8. Allylation of Carbon Pronucleophiles with Alkynes in the Presence of Palladium/Acetic Acid Catalyst
Nitin T. Patil, Isao Kadota, Akinori Shibuya, Young Soo Gyoung and Yoshinori Yamamoto*, Adv. Synth. Catal., 2004, 346, 800 - 804.
7. An Improved Catalytic System, Pd(PPh3)4/PhCOOH Combined Catalyst, for the Allylation of Carbon Pronucleophiles with Allenes
Nitin T. Patil, Nirmal K. Pahadi and Yoshinori Yamamoto*, Synthesis, 2004, 12, 2186 - 2190.
6. Enantioselective Catalytic Allylation of Carbonyl Groups by Umpolung of π-Allyl Palladium Complexes
Nitin T. Patil and Yoshinori Yamamoto*, Chemtracts, 2004, 17, 600 - 605.
Publications from Ph. D. Work :
5. Concise and Practical Synthesis of (2S, 3R, 4R, 5R) and (2S, 3R, 4R, 5S)-1,6-Dideoxy-1,6-iminosugars
Jayant N. Tilekar, Nitin T. Patil, Harishchandra S. Jadhav and Dilip D. Dhavale*, Tetrahedron, 2003, 59, 1873 - 1876.
4. 1-Aza-sugars from D-Glucose. Preparation of 1-Deoxy-5-(dehydroxymethyl) nojirimycin, its Analogues and Evaluation of Glycosidase Inhibitory Activity
Nitin T. Patil, Sheeja John, Sushma G. Sabharwal and Dilip D. Dhavale*, Bioorg. Med. Chem., 2002, 10, 2155 - 2160.
3. A Short and Efficient Synthesis of 1-Deoxy-castanospermine and 1-Deoxy-8a-epi-castanospermine
Nitin T. Patil, Jayant N. Tilekar and Dilip D. Dhavale*, Tetrahedron Lett., 2001, 42, 747 - 749.
2. Intermolecular Michael Addition of Substituted Amines to Sugar Derived α, β-Unsaturated Ester: Synthesis of 1-Deoxy-D-gluco- and L-ido-homonojirimycin, 1-Deoxy- castanospermine and 1-Deoxy-8a-epi-castanospermine
Nitin T. Patil, Jayant N. Tilekar and Dilip D. Dhavale*, J. Org. Chem., 2001, 66, 1065 - 1074.
1. Synthesis of C1-C6 Segment of Carbonolide B: Wolf Rearrangement of Sugar α-Diazo Ketones
Jayant N. Tilekar, Nitin T. Patil and Dilip D. Dhavale*, Synthesis, 2000, 395 - 398.